Adding new member- can we select what calendar events they can automatically add to?

There is not presently a native method to do this in Scoutbook, but you can alter the invite list for any given calendar using the Feature Assistant Extension, created by @GaryFeutz, a volunteer scouter. There are instructions for bulk updating the invitee list in the help documentation for the FAE. There are links to installation instructions and the help documentation at the link I provided above.